A Review of Supercritical Technologies for Lipid-Based Biofuels Production: The Glycerol-free Processes

Authors

DOI:

https://doi.org/10.4186/ej.2021.25.2.1 Full article

Abstract

Supercritical transesterification of lipid-based biomasses, a recent technique to produce biofuel without a catalyst, is discussed. This review focused on a glycerol-free process. The supercritical reactants include dimethyl carbonate, diethyl carbonate, methyl acetate, ethyl acetate (ETA), and methyl tert-butyl ether. The by-products from the glycerol-free process can improve both the quantity and quality of the resultant biofuel. This review suggests that supercritical transesterification of lipid-based biomasses using ETA as a co-reactant can provide the most valuable advantages, as involves inexpensive and renewable resources, which are important for biofuel production and sustainability.

Keywords:

supercritical fluids, biofuel, biomass, oxygenated fuel, glycerol

Affiliations

  • Winatta Sakdasri Chulalongkorn University
  • Cholada Komintarachat Kasetsart University
  • Ruengwit Sawangkeaw Chulalongkorn University
  • Somkiat Ngamprasertsith Chulalongkorn University

Corresponding author: Somkiat Ngamprasertsith, somkiat.n@chula.ac.th

1077 1420

Author Biographies

  • Fuels Research Center, Department of Chemical Technology, Faculty of Science, Chulalongkorn University, Bangkok 10330, Thailand

    Program of Food Process Engineering, Faculty of Food-Industry, King Mongkut’s Institute of Technology Ladkrabang, Bangkok 10520, Thailand

  • Department of Basic Science and Physical Education, Faculty of Science at Si Racha, Kasetsart University, Sukhumvit Road, Si Racha, Chonburi 20230, Thailand

  • The Institute of Biotechnology and Genetic Engineering, Chulalongkorn University, Institute Bldg. 3, 254 Phayathai Rd., Pathumwan, Bangkok 10330, Thailand

    Research Unit in Bioconversion/Bioseparation for Value-Added Chemical Production, Institute of Biotechnology and Genetic Engineering, Chulalongkorn University, 254 Phayathai Road, Pathumwan, Bangkok, Thailand

  • Fuels Research Center, Department of Chemical Technology, Faculty of Science, Chulalongkorn University, Bangkok 10330, Thailand

    Center of Excellence on Petrochemical and Materials Technology, Chulalongkorn University, 254 Phayathai Road, Pathumwan, Bangkok 10330, Thailand

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How to Cite

[1]
W. Sakdasri, C. Komintarachat, R. Sawangkeaw, and S. Ngamprasertsith, “A Review of Supercritical Technologies for Lipid-Based Biofuels Production: The Glycerol-free Processes”, Eng. J., vol. 25, no. 2, pp. 1–14, Feb. 2021, doi: 10.4186/ej.2021.25.2.1.

Citations

Published

2021-02-28

Issue

Section

Environment, Energy and Natural Resources